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Visual Chemistry Encyclopedia 6 files - 711 sheets
Powerful visuals-complete coverage
 

File 3: Bonding and Gases

 
9x Atomic sand p orbitals (1)
9x Atomic d and f orbitals (2)
8x Molecular bonding in H2
9x Molecular bonding
6x Elements: radii and ionization
13x Structure: introduction
9x Methane and ethane: carbon Sp3 orbitals
6x Ehene and Ethyne: sp' and sp orbitals
6x Ethyne/acethylene
17x Shape of molecules (1)
12x Gases and pressure
8x Molar volume
9x PVT diagrams
11x Osmosis and vapour pressure
8x Phase diagrams
 

3.17
Atomic s and p orbitals (1)
3.17.1
Cutaway diagrams showing the shape of s orbitals (fig. 7.25 Eb)
3.17.2
A periodic table illustrating the building-up order (fig. 8.12 Eb)
3.17.3
Cross-sectional representations of s-orbital probability (fig. 7.24 Eb)
3.17.4
Probability distribution for the 1s wave function (Zu 58)
3.17.5
Hydrogen, 1s, 2s and 3s orbitals (Zu 60)
3.17.6 Radial probability distribution (Zu 59)
3.17.7 Transitions of the electron in the hydrogen atom (fig. 7.11 Eb)
3.17.8 Probability distribution cross section of 3p orbital (Zu 62)
3.17.9 The 2p orbitals (fig. 7.26 Eb)
   
3.18 Atomic d and f orbitals (2)
3.18.1 The d orbitals (Zu 213)
3.18.2

Orbital filling in the periodic table (Zu 68)

3.18.3 The five 3d orbitals (fig. 7.27 Eb)
3.18.4 The five d orbitals (fig. 23.22 Eb)
3.18.5 The transition metals (Zu 200)
3.18.6 Atomic radii of the 3d, 4d, and 5d transition series (Zu 203)
3.18.7 Boundary surfaces of the 4f orbitals (Zu 64)
3.18.8 Radical probability distributions for 3s, 3p and 3d orbitals (Zu 65)
3.18.9 Electron distribution for the argon atom (fig. 8.15 Eb)
   
3.19 Molecular bonding in H2
3.19.1 Formation of H2 (fig. 10.21 Eb)
3.19.2 Potential-energy curve for H2 (fig. 9.9 Eb)
3.19.3 Formation of bonding and antibonding orbitals in H2 (fig. 10.31 Eb)
3.19.4 Interaction of two H atoms and the energy profile (Zu 75)
3.19.5 The molecular orbitals for H2 (Zu 101)
3.19.6 Bond energies (in KJ/mol) (table 9.5 Eb)
3.19.7 Boundary surfaces of all 3d orbitals (Zu 63)
3.19.8 Boundary surface representations of 2p orbitals (Zu 61)
 
 
3.20 Molecular bonding
3.20.1 Sigma and pi bonds (fig. 10.26 Eb)
3.20.2 Overlap of the 1s and 2s orbitals in Li2 (Zu 102)
3.20.3 The atomic orbitals in B2 (Zu 103)
3.20.4 The orbitals for N2 (Zu 99)
3.20.5 The different ways in which 2p orbitals can interact (fig. 10.34 Eb)
3.20.6 The molecular orbitals from p atomic orbitals (Zu 104)
3.20.7 Bonding in HCI (fig. 10.22 Eb)
3.20.8 The molecular orbital diagram for HF (Zu 107)
3.20.9 Vibration of the HCI molecule (fig. 9.20 Eb)
   
3.21 Elements: radii and ionization
3.21.1 Representation of atomic radii of the main-group elements (fig. 8.17 Eb)
3.21.2 Atomic radius versus atomic number (fig. 8.16 Eb)
3.21.3 Ionization energy versus atomic number (fig. 8.18 Eb)
3.21.4 Electronegativities of the elements (fig. 9.12 Eb)
3.21.5 Electron affinity values (Zu 73)
3.21.6 Order of orbital filling in polyelectronic atoms (Zu 71)
   
3.22 Structure: introduction
3.22.1 The ligand arrangements for coordination n0 2, 4 and 6 (Zu 204)
3.22.2 The hybrid orbitals for various electron pair arrangements (Zu 100)
3.22.3 Arrangements of electron pairs around an atom yielding minimum repulsion (Zu 84)
3.22.4 Diagrams of hybrid orbitals (fig. 10.24 Eb)
3.22.5 Spatial arrangement of sp3 hybrid orbitals (fig. 10.23 Eb)
3.22.6 The orbitals for CO2 (Zu 98)
3.22.7 The electron distributions of the þ orbitals of O3 (fig. 10.38 Eb)
3.22.8 Relative energies of molecular orbitals (fig. 10.35 Eb)
3.22.9 The d orbitals in a tetrahedral arrangement of point charges (Zu 215)
3.22.10 The d energy diagrams for square, planar, and linear complexes (Zu 216)
3.22.11 Molecular orbital summary of second row diatomics (Zu 106)
3.22.12 First ionization energy values (Zu 72)
3.22.13 The d orbital energy level diagram for an octahedral complex (Zu 214)
    

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3.23 Methane and ethane: carbon sp3 orbitals (1)
3.23.1 The C-H bonds in methane (Zu 231)
3.23.2 The formation of sp3 hybrid orbitals (Zu 89)
3.23.3 The orbitals in CH4 (Zu 90)
3.23.4 The ethane structure (Zu 232)
3.23.5 The bonding in ethane (Zu 239)
3.23.6 The orbitals in NH3(Zu 91)
3.23.7 Molecular structure of NH3 (Zu 82)
3.23.8 Molecular structure of H2O (Zu 83)
   
3.24 Ehene and Ethyne: sp2 and sp1 orbitals
3.24.1 An sp2 hybridized C atom (Zu 93)
3.24.2 The formation of sp2 hybrid orbitals (Zu 92)
3.24.3 Sigma bonding in C2H4 (Zu 94)
3.24.4 Bonding in ethylene (fig. 10.27 Eb)
3.24.5 The bonding in ethylene (Zu 238)
3.24.6 Sigma and pi bonding (Zu 95)
   
3.25 Ethyne/acethylene
3.25.1 The bonding in acethylene (Zu 240)
3.25.2 Bonding in acethylene (fig. 10.28 Eb)
3.25.3 The formation of sp hybrid orbitals (Zu 97)
3.25.4 The orbitals for C2H4 (Zu 96)
3.25.5 The structures of PX3 and PX5 (Zu 196)
3.25.6 The structure of cis and trans Co(NH3)4Cl2 (Zu 207)
   
3.26 Shape of molecules (1)
3.26.1 The molecular structure for MX3, MX5 and MX6 (Zu 188)
3.26.2 Arrangement of electron pairs about an atom (fig. 10.3 Eb)
3.26.3 Molecular geometries (central atom with 2 to 4 pairs) (fig. 10.4 Eb)
3.26.4 Molecular geometries (central atom with 5 to 6 pairs part 1) (fig. 10.9 Eb)
3.26.5 The transition metals (Zu 201)
3.26.6 Trigonal bipyramidal arrangement of electron pairs (fig. 10.10 Eb)
3.26.7 Energy levels of d orbitals in an octahedral field (fig. 23.23 Eb)
3.26.8 Some common ligands (Zu 205)
 

3.27 Shape of molecules (2)
3.27.1 The structures of MX4+ and MX6- (Zu 189)
3.27.2 Possible electron arrangements for I3- ion (Zu 88)
3.27.3 Molecular geometries (central atom with 5 to 6 pairs part 2) (fig. 10.9 Eb)
3.27.4 Possible structures for XeF4 (Zu 87)
3.27.5 Molecular structure of PCl6- (Zu 86)
3.27.6 The structures of several known xenon compounds (Zu 199)
3.27.7 Octahedral electron arrangement for Xe (Zu 85)
3.27.8 Geometric isomers of tetraamminedichlorocobalt(III) ion (fig. 23.14 Eb)
3.27.9 Structure of tris(ethylenediamine)cobalt(III) ion (fig. 23.7 Eb)
   
3.28 Gases and pressure
3.28.1 Observing the vapour phenomenon (fig. 11.13 Eb)
3.28.2 Formation of cathode rays (fig. 2.4 Eb)
3.28.3 The scanning tunneling microscope (fig. 7.21 Eb)
3.28.4 How a compact disc player works (fig. 7.15 Eb)
3.28.5 A ruby laser (fig. 7.14 Eb)
3.28.6 A mercury barometer (fig. 5.2 Eb)
3.28.7 Deflection of cathode rays (Zu 11)
3.28.8 Torricellian barometer (Zu 32)
3.28.9 Measurement of the vapour pressure of water (fig. 11.4 Eb)
3.28.10 Simple manometer (Zu 33)
3.28.11 Boyle’s experiment (fig. 5.5 Eb)
3.28.12 Gas pressure-volume relationship: V vs. P (fig. 5.6A Eb)
3.28.13 Pressure-volume product of gases at different pressures (fig. 5.26 Eb)
3.28.14 Gas pressure-volume relationship: 1/V vs. P (fig. 5.6B Eb)
3.28.15 Linear relationship of gas volume and temperature - constant P (fig. 5.8 Eb)
   
3.29 Molar volume
3.29.1 Kinetic-theory model of gas pressure (fig. 5.18 Eb)
3.29.2 Concentration of a gas is proportional to the pressure (fig. 14.4 Eb)
3.29.3 Effect of molecular volume at high pressure (fig. 5.27 Eb)
3.29.4 Increasing T of a sample gas at a constant P (Zu 39)
3.29.5 Molar volume of a gas (fig. 5.10 Eb)
3.29.6 Gay-Lussac’s combining gas volumes results (Zu 9)
3.29.7 Combining gases at the molecular level (Zu 10)
3.29.8 Increasing the number of moles of gas particles at constant P and T (Zu 40)
   
3.30 PVT diagrams
3.30.1 Effect of intermolecular attractions on gas pressure (fig. 5.28 Eb)
3.30.2 Decreasing V of a sample gas at constant T (Zu 37)
3.30.3 Plotting Boyle’s data (Zu 34)
3.30.4 Plot of PV versus P for gases at low pressure (Zu 35)
3.30.5 Plots of V versus T (Zu 36)
3.30.6 Increasing T of a sample gas at a constant V (Zu 38)
3.30.7 The hypothetical contraction of a gas (Zu 170)
3.30.8 Plots of PV/nRT versus P (Zu 44)
3.30.9 Plots of PV/nRT versus P for N2 gas (Zu 45)
   
3.31 Osmosis and vapor pressure
3.31.1 Heating curve for water (Zu 129)
3.31.2 The phase diagram for water (Zu 131)
3.31.3 Heating curve for water (fig. 11.9 Eb)
3.31.4 An aqueous solution and pure water in a closed environment (Zu 136)
3.31.5 Effect of pressure on gas solubility (fig. 12.12 Eb)
3.31.6 An experiment in osmosis (fig. 12.22 Eb)
3.31.7 Demonstration of vapor-pressure lowering (fig. 12.15 Eb)
3.31.8 The development of osmotic pressure (Zu 138)
3.31.9 Vapor diagrams for an aqueous solution (Zu 137)
3.31.10 Effect of a nonvolatile solute on freezing and boiling points (fig. 12.18 Eb)
3.31.11 Effusion of a gas (Zu 43)
   
3.32 Phase diagrams
3.32.1 Finding the vapour density of a substance (fig. 5.14 Eb)
3.32.2 Solid and liquid phases in equilibrium with the vapor phase (Zu 130)
3.32.3 Phase diagram for water (fig. 11.11 Eb)
3.32.4 The phase diagram for carbon (Zu 132)
3.32.5 The phase diagram for carbon dioxide (Zu 133)
3.32.6 Diagrams showing the reason vapor pressure depends on temperature (Zu 128)
3.32.7 Distribution of molecular velocities of O2 at STP (Zu 41)
3.32.8 Velocity distribution of N2 at three temperatures (Zu 42)
   
 
 
 
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